3D Organic–Inorganic Perovskite Ferroelastic Materials with Two Ferroelastic Phases: [Et3P(CH2)2F][Mn(dca)3] and [Et3P(CH2)2Cl][Mn(dca)3]

Organic–inorganic hybrid perovskite-type multiferroics have attracted considerable research interest owing to their fundamental scientific significance and promising technological applications in sensors and multiple-state memories. The recent achievements with divalent metal dicyanamide compounds revealed such malleable frameworks as a unique platform for developing novel functional materials. Herein, two 3D organic–inorganic hybrid perovskites [Et₃P(CH₂)₂F][Mn(dca)₃] ( 1 ) and [Et₃P(CH₂)₂Cl][Mn(dca)₃] ( 2 ) (dca=dicyanamide, N(CN)₂⁻) are presented. Accompanying the sequential phase transitions, they display a broad range of intriguing physical properties, including above room temperature ferroelastic behavior, switchable dielectricity, and low-temperature antiferromagnetic ordering (T_c=2.4 K for both 1 and 2 ). It is also worth noting that the spontaneous strain value of 1 is far beyond that of 2 in the first ferroelastic phase, as a result of the precise halogen substitution. From the point view of molecular design, this work should inspire further exploration of multifunctional molecular materials with desirable properties.     

The peeling property of Bondi-Sachs metrics for nonzero cosmological constants

In this paper, we show that the peeling property still holds for Bondi-Sachs metrics with nonzero cosmological constants under the boundary condition given by Sommerfeld's radiation condition together with three nontrivial Λ-independent functions B, a and b. This should indicate that the new boundary condition is natural. Moreover, we construct some nonstationary vacuum Bondi-Sachs metrics without Bondi news, whose Newman-Penrose quantities fall faster than usual. This provides a new feature of gravitational waves for nonzero cosmological constants.     

利用信号自相关函数warping变换的浅海水下移动观测平台机动优化方法

水下移动观测平台的机动航路对纯方位目标运动分析方法的使用性能具有重要的影响。针对此问题,提出了一种利用信号自相关函数warping变换的浅海水下移动观测平台机动优化方法。该方法利用warping变换从接收信号自相关函数中提取与目标距离相关的简正波相干项的特征频率,进而估计距离特征量,再根据预估的目标初始距离范围估计目标运动态势范围。针对观测平台机动方式为匀速转弯运动的情况,以目标方位变化率为评价指标得到了观测平台在所估计的目标运动态势范围下的最优转弯角速率。在浅海Pekeris波导环境下的数值仿真结果和实验数据处理结果表明:方位变化率与纯方位扩展卡尔曼滤波算法的性能密切相关;利用warping变换可以有效地估计距离特征量;观测平台根据以方位变化率为评价指标得到的最优转弯角速率进行机动可以获得较好的目标跟踪性能,收敛时间较短,目标位置估计误差较小。      

水平阵信号压缩感知用于简正波分离

针对水平阵信号简正波分离过程中常规波束形成分辨率低以及warping模态滤波不适用于复杂声信号的问题,提出水平阵信号压缩感知用于简正波分离的方法。利用压缩感知在方位估计中的高分辨特性,通过估计水平阵接收信号在频率方位角上的二维分布,分离得到各阶简正波的方位谱,并逆Fourier变换得到时域波形。仿真孔径1 km、阵元间隔10 m水平阵接收20~200 Hz伪随机声信号和脉冲声信号,所提方法分离出的各阶简正波与理论波形的相关系数在0.97~1.0。对2011年北黄海声学实验中的海底28元水平阵接收的气枪信号,在合成至1 km孔径后使用压缩感知方法分离简正波,其与warping模态滤波分离得的前5阶简正波相关系数在0.82~0.93。仿真与实验都说明了水平阵信号压缩感知简正波分离方法的有效性。      

Lattice-confined Ru clusters for hydrogen oxidation reaction with high CO-tolerance

正Hydrogen has been considering as a promising renewable energy source and a viable alternative for fossil-fuels in the future [1,2]. Hydrogen oxidation reaction (HOR) and its reverse reaction are two significant reactions for applying hydrogen as electrochemical energy. On the other hand,platinum is believed to be the best electrocatalyst for HOR,although several drawbacks including high cost, scarcity,low CO tolerance, and depressed catalytic activities in alkaline environments, hinder the development of hydrogen application [1]. Hence, it is highly desired to develop Pt-free HOR catalysts with high activity, high stability, low cost, and good resistance to CO poisoning [3].     

光驱动C1转换到高附加值化学品的研究进展

阐述了光驱动C1化学的最新研究进展, 分别对光驱动费托合成、 水煤气变换、 二氧化碳加氢、 甲烷重整和甲醇重整制氢的研究进行了综述, 提出了当前研究存在的问题及发展方向.     

Synthesis and Applications of SAPO-34 Molecular Sieves

Silicoaluminophosphate zeolite (SAPO-34) has been attracting increasing attention due to its excellent form selection and controllability in the chemical industry, as well as being one of the best industrial catalysts for methanol-to-olefin (MTO) reaction conversion. However, as a microporous molecular sieve, SAPO-34 easily generates carbon deposition and rapidly becomes inactivated. Therefore, it is necessary to reduce the crystal size of the zeolite or to introduce secondary macropores into the zeolite crystal to form a hierarchical structure in order to improve the catalytic effect. In this review, the synthesis methods of conventional SAPO-34 molecular sieves, hierarchical SAPO-34 molecular sieves and nanosized SAPO-34 molecular sieves are introduced, and the properties of the synthesized SAPO-34 molecular sieves are described, including the phase, morphology, pore structure, acid source, and catalytic performance, in particular with respect to the synthesis of hierarchical SAPO-34 molecular sieves. We hope that the review can provide guidance to the preparation of the SAPO-34 catalysts, and stimulate the future development of high-performance hierarchical SAPO-34 catalysts to meet the growing demands of the material and chemical industries.     

A multigrid method for the ground state solution of Bose–Einstein condensates based on Newton iteration

BIT Numerical Mathematics - In this paper, a new kind of multigrid method is proposed for the ground state solution of Bose–Einstein condensates based on Newton iteration scheme. Instead of...